Self-dispersion of mercury metal into aqueous solutions

Mercury metal dispersed spontaneously into the aqueous solution as micro-droplets when it came in quiescent contact with the solution. The self-dispersion was observed by means of the dynamic light scattering method, thermogravimetry and voltammetry. The mercury microdroplets generated in water had ca. 0.3 m in diameter. The diameter and the concentration of the droplets were stable. The concentration of mercury might be 1-3 mol dm if the droplets were to be dissolved homogeneously in water. The concentration exceeds the environmental limits by three orders of magnitude. The dispersed mercury was confirmed not to be ions or oxide of mercury but to be metal droplets. The self-dispersion of mercury belongs to the self-emulsification at liquid|liquid interfaces without surfactants. key words: micro-droplets of mercury; self-emulsification; dynamic light scattering; stripping voltammetry * Corresponding author, Tel: +81 776 27 8665, fax: +81 776 27 8494 E-mail: [email protected]